benzophenone

Benzophenone (CAS 119-61-9, molecular formula C₁₃H₁₀O) is a white crystalline aromatic ketone used as a UV absorber and photoinitiator across a wide range of industrial and cosmetic applications. It is a standard ingredient in UV-curable inks, protective coatings, adhesives, plastics, and sun care products. In Pakistan, it is sourced through specialist importers and chemical distributors who serve the printing, packaging, and personal care sectors.

If your business sits anywhere in the manufacturing chain  cosmetics, printing inks, coatings, adhesives, or plastics, benzophenone is likely already part of your supply ecosystem. Yet most procurement teams underestimate its regulatory complexity and sourcing sensitivity until a supplier disruption or a regulatory change forces the issue.

This guide gives you a factual, practical understanding of what benzophenone is, how it works, where it is used, what safety and regulatory considerations apply, and how to procure it reliably within Pakistan’s B2B chemicals market.

What Is Benzophenone? Definition, Chemical Profile, and Key Properties

Benzophenone is the simplest diaryl ketone, formed by two benzene rings joined through a central carbonyl group (C=O). Its IUPAC name is diphenylmethanone. Although it occurs naturally in trace amounts in some fruits, plants, and fungi, its commercial form is synthetically produced through either catalytic air oxidation of diphenylmethane or Friedel-Crafts acylation of benzene with benzoyl chloride.

Key chemical properties of benzophenone:

  • CAS Number: 119-61-9
  • Molecular Formula: C₁₃H₁₀O (also written as (C₆H₅)₂CO)
  • Molecular Weight: 182.22 g/mol
  • Physical Form: White crystalline solid
  • Odor: Faint rose-like or geranium floral
  • Melting Point: 48.5°C
  • Boiling Point: 305.4°C
  • Density: 1.11 g/cm³
  • Solubility: Practically insoluble in water; readily soluble in ethanol and ether
  • Flash Point: Approximately 110°C

These properties make benzophenone a chemically stable, easy-to-handle material that integrates cleanly into industrial and cosmetic formulations alike.

How Does Benzophenone Work? UV Absorber vs. Photoinitiator Explained

Benzophenone performs two commercially distinct functions depending on how it is applied. Understanding the difference is critical for formulators and procurement teams sourcing it for specific applications.

Benzophenone as a UV Absorber

As a benzophenone UV absorber, the compound uses its conjugated aromatic-carbonyl structure to absorb ultraviolet radiation in the 260 to 350 nm wavelength range. When UV light strikes the molecule, electrons are promoted through a pi-pi* transition. The absorbed energy is then converted into harmless heat through non-radiative energy dissipation, protecting underlying materials from photodegradation.

In practical terms, this means less color fading, less yellowing, less brittleness, and longer product life for polymers, pigments, packaged goods, and treated surfaces exposed to sunlight or UV lamp sources.

Benzophenone as a Photoinitiator in UV Curing

When used as a benzophenone as a photoinitiator, the mechanism is different. On UV exposure, benzophenone reaches its triplet excited state with near-100% efficiency. In the presence of a tertiary amine co-initiator, it abstracts a hydrogen atom from the amine, generating free radicals. These radicals initiate rapid crosslinking of acrylate or methacrylate monomers, curing the ink, coating, or adhesive layer within fractions of a second.

This is a Type II photoinitiator mechanism. It is the scientific foundation of UV-curing technology, and benzophenone is one of the most widely used molecules in this category globally.

What Is Benzophenone Used For? Key Industrial Applications

Benzophenone uses and applications span multiple sectors. Each use case leverages a distinct combination of its UV-absorbing and radical-generating capabilities.

Benzophenone in UV-Curable Inks and Printing Processes

Benzophenone in UV-curable inks is one of its highest-volume industrial applications. It is a core photoinitiator in three major commercial printing formats:

  • Benzophenone in flexographic printing: Used in high-speed label, flexible packaging, and corrugated board printing where fast UV cure enables continuous production runs.
  • Benzophenone in screen printing: Used in textile, graphic, and industrial screen printing for instant surface cure and high durability.
  • Benzophenone in gravure printing: Used in publication and packaging gravure where consistent ink cure quality is essential at high speeds.

Benzophenone in printing inks also contributes to color stability, scratch resistance, and gloss, while significantly reducing volatile organic compound (VOC) emissions compared to solvent-based ink systems. This is both a performance and a sustainability advantage.

Benzophenone in UV Coatings and UV Adhesives

Benzophenone in UV coatings functions as both a photoinitiator and a UV stabilizer. It is used in clear topcoats, protective varnishes, wood finishes, optical coatings, and metal surface treatments where fast cure and long-term UV durability are both required.

Benzophenone in UV adhesives enables precision, on-demand bonding in electronics assembly, optical device manufacturing, medical device production, and structural bonding applications. UV trigger activation allows positioning and alignment before instant cure, which is a critical process control advantage.

Benzophenone in Plastics and Polymer Stabilization

Benzophenone in plastics is used as an additive UV stabilizer that protects polyolefins, PET, polycarbonate, and acrylic resins from photodegradation caused by prolonged UV exposure.

Benzophenone in polymer stabilization is especially relevant in clear and transparent packaging, where opaque or colored UV-blocking materials are not an option. It allows manufacturers to retain optical clarity in PET bottles, blister packs, and transparent films while protecting both the polymer structure and the packaged product from UV damage. This directly extends shelf life and protects product integrity.

Benzophenone in Cosmetics and Sun Care

Benzophenone and its derivatives serve as UV filters in sunscreens, moisturizers, lip balms, nail care products, hair care formulations, and fragrance products. The parent compound also functions as a fragrance fixative, contributing a rose-geranium note and stabilizing scent and color in perfumes and personal care products.

Benzophenone Derivatives: Types, Functions, and Regulatory Standing

The benzophenone family includes multiple derivatives used across sun care, personal care, and industrial applications. Their functional and regulatory profiles differ significantly.

DerivativeCAS NumberPrimary FunctionKey Use CaseCurrent Regulatory Status
Benzophenone (Base)119-61-9UV absorber / Type II photoinitiatorUV inks, coatings, adhesives, plasticsIARC Group 2B; Prop 65 listed
Benzophenone-1 (BP-1)131-56-6UV filter / UV stabilizerSunscreens, colorant protectionEU SCCS: NOT safe for cosmetics (March 2025)
Benzophenone-3 (Oxybenzone)131-57-7Broad-spectrum UVA/UVB filterSunscreens, lotions, plasticsEU/UK restricted; ECHA endocrine disruptor (Aug 2025)
Benzophenone-4 (Sulisobenzone)4065-45-6Water-soluble UVA filterSun care, color protectionUnder SCCS review
Benzophenone-56628-37-1UVA filter (sodium salt of BP-4)Sun care, shelf-life extensionEU SCCS: safe up to 5% (June 2025)

The base compound drives industrial performance. Derivatives like benzophenone-3 (oxybenzone) dominate global sun care formulation but face accelerating restrictions. Any cosmetic formulator working with EU or UK export markets must track derivative-level regulatory status separately from the base compound.

Health, Safety, and Regulatory Status of Benzophenone

Benzophenone sits in a nuanced regulatory position. It is not universally prohibited, but it carries real regulatory obligations that vary by market and application.

  • Carcinogenicity: The International Agency for Research on Cancer (IARC) classifies benzophenone as Group 2B, meaning possibly carcinogenic to humans. California’s Prop 65 added it to the carcinogen list effective June 22, 2012, with product warning requirements from June 22, 2013.
  • US FDA: In 2018, the FDA removed benzophenone from its approved list of synthetic food flavoring additives under the Delaney Clause, which prohibits food additives shown to cause cancer in animals  even at doses far higher than real-world exposure. The FDA stated explicitly that benzophenone does not pose a public health risk at intended use levels; the action was a legal requirement under the statute, not a risk-based finding.
  • EU Cosmetics Regulation: Benzophenone-3 is restricted under Commission Regulation (EU) 2022/1176. Maximum permitted concentrations are 6% in face, hand, and lip products; 2.2% in body products and sprays; and 0.5% in all other product types. Products containing more than 0.5% benzophenone-3 must carry the label “Contains Benzophenone-3.” The UK adopted equivalent limits effective January 21, 2026.
  • SCCS 2025 Opinions: The EU Scientific Committee on Consumer Safety (SCCS) concluded in March 2025 that benzophenone-1 is unsafe for cosmetic use due to genotoxicity and estrogenic activity. It could not conclude benzophenone-2 is safe for similar reasons, while benzophenone-5 was deemed safe at up to 5%.
  • Industrial handling: Standard precautions apply. Use gloves, eye protection, and adequate ventilation. Store in cool, dry, dark conditions away from heat sources and incompatible oxidizing agents.

Environmental Concerns: Benzophenone and Marine Safety

Oxybenzone (benzophenone-3) has been linked to coral bleaching and developmental harm in marine organisms at low environmental concentrations. Stanford University research found that oxybenzone can be converted into a phototoxin inside coral and anemone cells under sunlight exposure.

Hawaii enacted the first US statewide ban on oxybenzone-containing sunscreens in 2018, effective January 1, 2021. Key West, Palau, Bonaire, and Aruba implemented similar restrictions.

The base benzophenone compound itself carries the H411 aquatic hazard classification: toxic to aquatic life with long-lasting effects. Industrial operations handling benzophenone in volume should implement wastewater controls accordingly.

For cosmetic manufacturers targeting export, reef-tourism, or eco-conscious consumer markets, transitioning to mineral sunscreen actives or next-generation organic UV filters is both a regulatory and commercial strategy.

Benzophenone in Pakistan: Market Demand, Pricing, and Sourcing

Benzophenone in Pakistan is entirely import-dependent. There is no known domestic production. Primary supply comes from manufacturers in China and India, imported under HS code 2914.39. Cosmetic-grade derivatives such as oxybenzone may also be classified under HS 2914.50 depending on form and specification.

Demand is driven by two sectors. Pakistan’s printing and packaging industry is estimated at approximately USD 5.4 billion, growing 4 to 10% annually, and is the second-largest packaging sector in South Asia. UV-curable printing operations across this sector require benzophenone photoinitiator Pakistan as a standard production input. The personal care and cosmetics market is estimated at USD 5.10 billion in 2025, pulling demand for UV filter ingredients at both formulation and contract manufacturing levels.

Benzophenone price in Pakistan benchmarks against international sourcing costs.

Technical-grade material FOB China runs approximately USD 1.8 to 2.0 per kilogram (Q1 2026 reference). Small-lot and cosmetic-grade orders carry a premium above these levels depending on purity specification and documentation requirements.

Sourcing ParameterDetail
HS Code (Base Compound)2914.39
HS Code (Some Derivatives)2914.50
Primary Import OriginsChina, India
Technical-Grade Price ReferenceUSD 1.8 to 2.0/kg FOB China (Q1 2026)
Cosmetic-Grade PricingPremium above technical-grade; COA/MSDS required
Key Distribution HubsKarachi, Lahore, Faisalabad
Critical DocumentationCertificate of Analysis (COA), Material Safety Data Sheet (MSDS), purity specification
Lead Time ConsiderationImport-dependent; advance procurement recommended

Benzophenone Suppliers and Alternatives in Pakistan

Benzophenone suppliers in Pakistan and benzophenone importers in Pakistan are concentrated in Karachi’s chemical trading zones, with distribution networks extending to benzophenone distributors in Karachi, benzophenone suppliers in Lahore, and benzophenone Faisalabad-based industrial customers. When you buy benzophenone in Pakistan, always request a current COA and ensure the purity grade matches your application. For cosmetic-grade material, verify that concentrations align with applicable regional regulatory limits before formulation.

Benzophenone wholesale Pakistan buyers benefit from forward procurement planning given import lead times. Stexol Chemicals is a specialist supplier of cosmetic raw materials in Pakistan, offering quality-certified UV-active ingredients with full documentation, flexible order quantities, and supply-chain support for small and medium-scale manufacturers. Bulk orders of benzophenone can be placed directly through Stexol Chemicals, making it a reliable single-source option for manufacturers looking to consolidate their raw material procurement.

Benzophenone manufacturers in Pakistan do not currently exist at commercial scale, which makes supplier selection and import-chain reliability critical procurement decisions.

Benzophenone-Free Alternatives: When and Why to Switch

Not every market or application requires benzophenone. Understanding when alternatives are appropriate prevents unnecessary reformulation while also preventing regulatory exposure.

For cosmetic and sun care formulations targeting EU, UK, or reef-sensitive export markets:

The lowest-risk substitution path is mineral UV protection using zinc oxide and/or titanium dioxide. These are the only two UV filters the US FDA classifies as generally recognized as safe and effective (GRASE). Both are reef-compatible in non-nano particle form, carry minimal regulatory risk globally, and align with clean beauty positioning. Limitations include white-cast appearance at higher concentrations and weaker long UVA coverage for titanium dioxide without formulation adjustments.

Next-generation organic UV filters such as bis-ethylhexyloxyphenol methoxyphenyl triazine (Tinosorb S) offer broad-spectrum coverage with strong safety profiles in EU-approved markets, though not all have FDA clearance.

For UV-curing applications in food-contact packaging:

Low-migration polymeric benzophenone derivatives and alternative Type I photoinitiator chemistries are the standard industry response to food-contact migration concerns. UV-LED curing systems operating at specific wavelengths also allow reformulation away from benzophenone-type chemistry entirely, though capital investment and ink system changes are required.

For domestic Pakistan cosmetic manufacturers with no current export obligation:

No formal benzophenone restriction applies under current Pakistani regulation. However, Pakistan’s developing cosmetic regulatory framework and growing alignment with international standards make proactive reformulation planning a sound medium-term strategy rather than a reactive one.

Ready to source benzophenone or UV-active raw materials for your production line?

Stexol Chemicals supplies quality-certified cosmetic and industrial chemical ingredients to manufacturers across Pakistan with full documentation, reliable lead times, and order flexibility designed for small to medium-scale operations. 

Contact us today and get the right-grade material your formulation actually needs.